Semiconductor fundamentals can be summarized as follows:
1) Conductors, insulators, and semiconductors differ in their ability to conduct electricity based on their energy band structure and band gap. Conductors have overlapping or partially filled bands allowing electron flow, insulators have a large band gap suppressing flow, and semiconductors have a small band gap allowing some flow.
2) Intrinsic semiconductors like silicon are pure, while extrinsic semiconductors are doped with impurities to create excess electrons (n-type) or holes (p-type) improving conductivity.
3) A pn junction diode allows current in one direction by forward biasing the junction