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CLASS 12
CHAPTER 2 - SOLUTIONS
RECAP
▪ Introduction
▪ Expressing concentration of solution
quantitatively
TOPICS
▪ Mole fraction
▪ Molarity
▪ Molality
Mole Fraction
Mole fraction
of that
component
Number of moles of
that component
Total number of moles of
all the components
=
Denoted by the letter chi or Roman x
Mole Fraction
Ex: Binary Solution
Ex: Calculate the mole fraction of ethylene glycol (C2H6O2) in
a solution containing 20% of C2H6O2 by mass.
Class 12, subject chemistry chapter name   solutions, topic name - expressing concentration of solution and problems
Molarity
Molarity
Moles of solute
Volume of solution in litre
=
Denoted by the letter M (molar)
Defined as number of moles of solute dissolved in one
litre (or one cubic decimetre) of solution.
Molarity
Ex: 0.25 M solution of NaOH means that 0.25 mol of NaOH
has been dissolved in one litre.
Ex: Calculate the molarity of a solution containing 5g of NaOH
in 450 mL solution.
Molality
Molality
Moles of solute
Mass of solvent in kg
=
Denoted by the letter m
Defined as number of moles of solute per kilogram
(kg) of the solvent
Molality
Ex: 1m solution of KCl means that 1 mol (74.5g) of KCl is
dissolved in 1 kg of water.
Ex: Calculate the molality of 2.5g of ethanoic acid (CH3COOH)
in 75g of benzene.
Comparing Molarity and Molality
Problem 1: Calculate the mass percentage of benzene (C6H6)
and carbon tetrachloridre (CCl4) if 22g of benzene is dissolved
in 122g of CCl4.
Class 12, subject chemistry chapter name   solutions, topic name - expressing concentration of solution and problems
Problem 2: Solution of glucose in water is labelled as 10% w/w,
what would be the molality and mole fraction of each component
in the solution? If the density of solution is 1.2 g mL-1,
then what shall be the molarity of the solution?
Class 12, subject chemistry chapter name   solutions, topic name - expressing concentration of solution and problems
Class 12, subject chemistry chapter name   solutions, topic name - expressing concentration of solution and problems
Class 12, subject chemistry chapter name   solutions, topic name - expressing concentration of solution and problems

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