Complexometric titrations with EDTA
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The document provides an overview of complexometric titration, detailing the use of EDTA as a chelating agent, types of titrations, and the importance of metallochromic indicators in visually detecting end points. It explains the mechanisms of EDTA titration with examples, including direct and back titrations, and discusses methods for enhancing selectivity through masking and demasking agents. Additionally, it outlines the stoichiometry, conditions for complex formation, and references for further reading.
Complexometric titrations with EDTA
- 2. Complexometric Titration EDTA as a Chelating Agent Role of Metallochromic Indicator Mechanism of Titration with EBT Indicator Requirements for visual Detection Types of EDTA Titration Methods of Increasing Selectivity for Complexation Analysis of a Metals Mixture References
- 3. .. Type of volumetric analysis. A colored complex formed between metal and ligand. Ligands are used for complexations. Indicator is used to indicate the end point of a titration. M+ + L M-L
- 4. ..
- 5. EDTA forms stable complex with various metal ions i.e. high Kf values. The complexation occurs in single step. sharp change in the metal ion conc. At the equivalence point. The M-EDTA complexes are water soluble. The Stoichiometry for all metal ions is same 1:1 irrespective of its charge.
- 6. .. Hydrolysis of certain metal ions occurs at high pH. At low pH EDTA loses its ability to donate its lone pairs. EDTA lacks selectivity i.e. Forms stable complexes with various metals.
- 7. Fast sulphon black F Calcon Xylenol orange
- 9. Metal Metallochromic Indicators metal-indicator complex Low stability constant Chelate-metal complex High stability constant At equivalence point Indicator get free to produce color
- 10. EDTA Colorless Zn+2 Colorless EBT Wine red Color Complex is formed Blue EBT EBT + Min Mechanism of Titration With EDTA and EBT indicator
- 11. ..
- 12. The requirement of a metal ion indicator for use in the visual detection of end points include: The color change must be sharp. The pH of the solution should not very high. The MIn complex must possess sufficient stability. The MIn complex must be less stable than the M- EDTA complex.
- 13. Types Of EDTA titrations Direct Titrations Back Titrations Indirect Titrations Replacement Titrations
- 14. • It is the simplest method in which the standard solution of EDTA is slowly added to the metal ion solution till the end point. Mmols of std.EDTA added Mmols of metal in the sample
- 15. Back titration • This method is suitable when; • The reaction of metal ion with EDTA is slow , • The metal ion precipitates. • No suitable indicator is available Std.EDTA added in excess Exc.EDTA+ std.Metal =mmols of exc EDTA Total EDTA –Exc.EDTA=mmols of Metal in sample
- 16. • When direct or back titrations do not give sharp end points. • when there is no suitable indicator for the analyte. Mg-EDTA Ca+2 sample EDTA Ca+2 ions Mg-EDTA Mg+2 ions EDTA Mmols of EDTA= mmols of Ca+2
- 17. • Certain anions that form precipitate with metal cations and do not react with EDTA can be analyzed indirectly. SO4 -2, PO4 -3, can be determined by this method. • e.g. SO4 -2 can be determined by adding excess of Ba+2 to precipitate as BaSO4 . The precipitate is filtered and washed . • The excess Ba+2 in the filtrate is then titrated with EDTA.
- 18. pH control Use of masking and demasking agents Classical separation Kinetic masking
- 19. • The formation of a metal chelate complex dependent on the pH of the medium. • In weakly acid solution, the chelates of many metals such as alkaline earth metals are completely dissociated, whereas • chelates of Bi+3, Fe2+ or Cr+2 are readily formed at this pH.
- 21. .. Masking agents: • They prevent interfering ion from reaction without physical separation. • These reagents form complexes with interfering ions. • They form more stable complexes then ind. & EDTA Example; fluorides, cyanides etc.
- 22. Demasking agent : are reagents which regain the ability of masked ion to enter the reaction with ind. and EDTA. Example: • The masking by CN– can be removed by: • Mixture of formaldehyde – acetic acid
- 23. These are attempted only be applied if they are not tedious; further only those precipitates may be used for separations in which, after being re- dissolved, the cations can be determined complexometrically. Some of the examples are CaC2O4, nickel dimethylglyoximate, and CuSCN
- 24. Kinetic masking The metal ion does not form a complex due to its kinetic inertness. Or it reacts slow. For example, the reaction of chromium (III) with EDTA is quite slow. It is, therefore, possible to titrate other metal ions which react rapidly without interference from Cr (III).
- 25. .. Mn+2,Mg+2sample pH 10 Buffer EBT indicator 40C EDTA EDTA NaF Std.Mn+2
- 26. .. Mmols of Mn+2=mmols of EDTA for both metals-mmols of Mg+2 F- + Mg+2=Mg(F)2 release EDTA+Mn+2= mmols of Mg+2 Mn+2,Mg+2+EDTA= mmols of EDTA for both metals
- 27. 1. https://www.slideshare.net/obydullah/complexometric- titrationsACS publications 2. https://pubs.acs.org/doi/pdf/10.1021/ed074p1463 3. http://www.srmuniv.ac.in/sites/default/files/downloads/Comple xometric_Titration.pdf 4. Instrumental skoog