Effect of soft segment chain length on tailoring the properties of isocyanate terminated polyurethane prepolymer, a base material for polyurethane bandage

IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
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Volume: 02 Issue: 10 | Oct-2013, Available @ http://www.ijret.org 395
EFFECT OF SOFT SEGMENT CHAIN LENGTH ON TAILORING THE PROPERTIES
OF ISOCYANATE TERMINATED POLYURETHANE PREPOLYMER, A BASE
MATERIAL FOR POLYURETHANE BANDAGE
Runumi Gogoi1
, M. Sarwar Alam2
,Utpal Kumar Niyogi3
1, 3
Material Science Division, Shriram Institute for Industrial Research, 19 University Road, Delhi 110007, India
2
Dept of Chemistry, Jamia Hamdard University, Hamdard Nagar, Delhi - 110062, India
Runumi@rediffmail.com
Abstract
Isocyanate terminated polyurethane prepolymer, a base material for water curable polyurethane bandage was prepared from
diphenylmethane diisocyanate and poly (propylene oxide) glycol. In polyurethanes, the diisocyanate act as hard segment and
provides dimensional stability, whereas the polyol which forms the soft segment gives elastomeric character. Due to its segmented
structure, polyurethane’s with a wide range of physico-mechanical properties can be obtained by varying its monomers types and
content. In this paper, the effect of different soft segment length on influencing the structure property relationship of polyurethane
prepolymer was studied. The soft segment length was varied by using poly (propylene oxide) glycol having different molecular weight
and also by blending two polyols having similar chemical composition but of different molecular weight. The formation of the
prepolymer was investigated by Fourier transform infrared spectroscopy (FTIR). The results reveal that with increasing soft segment
length, the weight average molecular weight and storage time of the prepolymer increases, whereas the Brookfield viscosity decreases
due to higher content of soft segment. The curing time was found higher in prepolymer having longer soft segments due to lower
isocyanate content. With increasing molecular weight of the soft segment, the phase separation between the hard and soft segment
increases due to which the prepolymer produce low Tg. The tensile strength of the polyurethane film decreases whereas percent
elongation increases with increase in soft segment length. The findings of the study will be beneficial for understanding the role
played by soft segment length on tailoring the structure and ultimately the properties of isocyanate terminated polyurethane
prepolymer.
Keywords: Polyurethane prepolymer, soft segment length, polyurethane bandage
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1. INTRODUCTION
Polyurethanes are block copolymers composed of alternating
soft and hard blocks or segment. The soft segment provides
elastomeric character to the polymer while the hard segment
forms dimensional stability. The soft segment with a low Tg
are formed from polyether or polyester, generally of mol.wt
400-5000. The rigid polar hard segments with a high Tg are
based on diisocyanate and low molecular weight chain
extender. At room temperature, the polyol segment are above
their Tg, so they are denoted as soft segment and the aromatic
diisocyanate which are below their Tg act as hard segment [1].
Because there exist a degree of thermodynamic immiscibility
between the hard urethane segments and the soft polyol
segments, polyurethane elastomers exhibit microphase
separation, which could result in a structure that can be
considered as hard segment domains dispersed in soft segment
matrix. Due to the presence of two phase micro domain
structure, the molecular structure of polyurethane can be
tailored to meet specific property requirement by varying the
hard and soft segment length and concentration [2].
The urethane linkage (-NH-COO-) in the polyurethane is a
result of the reaction between the diisocyanate (-NCO) groups
and polyol hydroxyl groups (-OH). If a stoichiometric excess
of diisocyanate is used, NCO terminated urethane chains are
produced and the product is called isocyanate terminated
prepolymer. The formation of isocyanate terminated
polyurethane prepolymer and its subsequent curing reaction
are represented schematically in scheme I. The curing of the
prepolymer takes place by coming in contact with water to
form a network of poly (urethane urea).

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2 OCN R NCO + HO R1 OH
OCN R N C
OH
O R' O C
O
N
H
RNCO + OCN R NCO(n-2)
Polyurethane prepolymer
Diisocyanate Polyol
HN R N C
OH
O O C
O
N
H
RR1CNH
O
NH C
O
NH + CO2
Urea Urethane
H2O
Scheme 1: Formation of isocyanate terminated polyurethane
prepolymer and its curing reaction
Many studies have been done in the past to observe the
structure property relationship of polyurethane. It was reported
in the literature that by varying the type and amount of polyol,
diisocyanate, catalyst, reaction time and temperature,
polyurethanes with a wide range of physico-mechanical
properties can be obtained [3]. It was also mentioned in the
literature that the prepolymer formation depends upon a
number of chemical factors. Among these, the degree of
branching (Mc) of polyol system and the equivalent weight of
the polyether or polyester greatly influence the formation of
the prepolymer [4].
The equivalent weight of polyol employed has a definite effect
on the viscosity buildup during the prepolymer formation. The
concentration of lower molecular weight polyol has more
influence on the viscosity than the concentration of higher
molecular weight polyol [3]. Also the number and size of diol
molecules which condense with diisocyanate, determines the
no of urethane linkages within the isocyanate terminated
prepolymer [3]. And the urethane group content determines
the degree of hardness and flexibility of the polyurethane [5].
In the field of coating technology, it was observed that the
chemical composition and molecular weight distribution
(MWD) of the incorporated soft block influence the
macroscopic properties of the resulting coatings [6].
The isocyanate terminated polyurethane prepolymers
synthesized in the present study will be applicable for
preparing water curable polyurethane bandage and for that
application, the proper choice of polyol molecular weight is
necessary to have proper mechanical strength, curing time and
storage stability. Thus, in the present study, a study was done
to see the effect of different soft segment chain length on the
physico-chemical, mechanical and thermal properties of
polyurethane prepolymer. The soft segment chain length was
varied by using poly (propylene oxide) glycol polyol having
different molecular weight and also by blending two polyols
of different molecular weight with the same chemical
composition. The isocyanate terminated polyurethane
prepolymer was synthesized by thermal polymerization
technique using diphenyl methane diisocyanate (MDI) and
poly (propylene oxide) glycol (PPG) at fixed isocyanate /
hydroxyl molar ratio. Their properties viz. physico-chemical,
mechanical, thermal and structures were investigated by
different ASTM and IS methods, thermal analysis, tensile test
and FTIR technique.
2. EXPERIMENTAL MATERIALS
Diphenyl methane diisocyanate (MDI) was obtained from
Sigma-Aldrich, USA. A white solid flakes (melt.pt. 40oC), it
was used as such without further purification. Poly (propylene
oxide) glycol (PPG) was obtained from Sigma-Aldrich, USA.
The polyol was vacuum dried for 2 hours at 80oC and kept
overnight in molecular sieves prior to use to ensure that the
material is free from moisture (less than 0.05%). The
properties of MDI and PPG used for the synthesis of
polyurethane prepolymer are given in Table I. Catalysts 2,2´
dimorpholino diethyl ether (DMDEE) from Degussa,
Germany was procured and used as such without any
purification.
Table 1: Some properties of MDI and PPG used for the prepolymer synthesis
Property MDI PPG400 PPG1000 PPG2000 PPG 2700
Average functionalitya 2.0 2.0 2.0 2.0 1.8
OH number (mg KOH/g)a 0.0 281 111 56 37
NCO content (wt%)b 33.8 0.0 0.0 0.0 0.0
Molecular weight (g/mol)a 250 400 1000 2000 2700
Viscosity 25oC, (cSt)a 50 99 150 300 627
a Information given by supplier
b Estimated by ASTM D2572 - 97(2010)

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2.1 Synthesis of Polyurethane (PU) Prepolymer
The synthesis was carried out in a 5-necked glass reactor
equipped with teflon stirrer, thermometer pocket, condenser
and nitrogen gas inlet system. The MDI was melted in a
beaker and poured into the reactor under nitrogen atmosphere.
Inert atmosphere was maintained throughout the reaction so as
to avoid the ingress of atmospheric moisture. The required
amount of catalyst (0.25% of the whole reaction mixture) was
then added followed by addition of PPG. The PPG was added
part wise to the reactor. After that, the system was maintained
at 60oC for 2 hours. The final prepolymer obtained was in the
form of a yellow colored viscous liquid.
The isocyanate terminated polyurethane prepolymers were
synthesized using different molecular weight of polyol (PPG
400, PPG 1000, PPG 2000, PPG 2700) and MDI at NCO / OH
molar ratio of 3:1. Mixed polyols i.e. PPG 1000 & PPG 400 in
50 / 50 ratio and PPG 2000 & PPG 400 in 50 / 50 ratio was
also used for synthesizing the prepolymer.
2.2 Preparation of Polyurethane Film
Polyurethane films were prepared by casting evaporation
technique. Approximately 10% solution of polyurethane
prepolymer in tetrahydrofuran was prepared and poured into a
Teflon mould. It was then kept at room temperature, till all the
solvent got evaporated and a transparent film was formed. The
films obtained were of about 0.4mm thickness.
2.3 Characterization
The following properties were characterized in the synthesized
prepolymers:
The Fourier Transform Infrared Spectroscopy (FTIR) spectra
of the prepolymers was taken on an FTIR, Perkin Elmer
Model 521 in the range of wavenumber from 400cm-1
to
4000cm-1
by coating 1mm thick layer of the prepolymer on a
KBr pellet.
The isocyanate content in the prepolymer was determined as
per ASTM D 2572-91. The isocyanate present in the
prepolymer was reacted with an excess of di-n-butyl amine
and then titrated with standard 0.1N HCl solution. Since a
known amount of amine was added, the amine consumed by
the prepolymer is due to the presence of free isocyanate which
was determined. The data given are the average of three
measurements.
Dynamic viscosity of the prepolymer was determined by
Brookfield viscometer DV Pro II (Brookfield Engineering
Laboratories Inc, USA). The measurements were performed at
35 ± 1o
C at 12rpm using spindle No.4.
The weight average molecular weight (Mw) of the prepolymer
was determined by gel permeation chromatography using
2414 RI Detector (Make –Waters) and polystyrene as a
standard. The samples were prepared in duplicate by
dissolving 0.5% and 0.1% by wt of prepolymer in
tetrahydrofuran (THF). THF was also used as a carrier solvent
at the rate of 0.5ml/min.
Storage time was determined as per the method mentioned in
US Patent 5,66,5056. For determining the storage stability
about 50 ml of the PU prepolymer is poured in a
polypropylene bottle and hermetically sealed under nitrogen
atmosphere. The bottle was kept in an oven controlled at
130C and the time till the resin was flow able was recorded.
An average of three measurements was taken as the result.
The set to touch time was determined according to ASTM
D1640 – 03 (2009). A thin film (approx thickness 12.5µm) of
PU prepolymer was coated on a glass plate. From time to time,
the tip of a clean finger was lightly touched on the test film
and immediately placed the fingertip on a piece of clean, clear
glass plate. Observed, if any of the prepolymer was transferred
to the glass plate If no prepolymer was transferred, the time
was noted as the set to touch time of the polyurethane
prepolymer. The test was carried out at 30-32o
C and relative
humidity of 40-45%. An average of three measurements was
taken as the result.
Tack-free time was determined according to IS 101 (Part
3/Sec1) -1986. A thin film of PU prepolymer was coated on a
glass plate. The plate was then placed in one pan of suitable
balance and counterpoised with weights. Placed a further
weight of 2.25kg and press on the dried film surface of the
plate with thumb till the two pans are balanced Hold for one
minute and then slowly release. If no sign of stickiness
appears on the thumb, the time was noted and reported as
tack-free time of the prepolymer. Temperature was maintained
at 30-32o
C and relative humidity of 40-45%. The data given
was the average of three measurements.
The tensile strength and percent elongation of the
polyurethane films were measured in a universal testing
machine (Tinius Olsen, H5KL). The dimension of the test
specimen was 10cm x 2cm x 0.04cm and the measurement
was performed under load cell of 250N with a crosshead speed
of 5mm/min at room temperature. The data taken are the
average of three measurements.
Differential Scanning Calorimetry (DSC) was carried out to
characterize the thermal properties of the prepolymer. The
measurements were carried out under nitrogen atmosphere on
a DSC – 2910 ( TA instrument). The heating rate was of 10o
C
/ min in the temperature range of -100o
C to 100o
C.

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3. RESULTS AND DISCUSSION
3.1 Influence of Soft Segment Length on Structure of
the Prepolymer
Fig- 1 shows the IR spectra’s of the synthesized prepolymers
using different polyol molecular weight. All the synthesized
prepolymer shows the characteristics absorption bands of
polyurethanes except in the peak associated to NCO
stretching which shows higher absorption area in case of
lower molecular weight polyol. This is due to the presence of
higher percent isocyanate content in case of lower molecular
weight polyol. It was observed that all the prepolymers
possess the following characteristic absorption bands, urethane
NH stretching at 3300cm-1
, bending at 1516cm-1
, methylene or
alkyl group at 2974cm-1
, carbonyl group at 1700cm-1
and C-O-
C stretching at 1100cm-1
. The strong characteristic peak at
2272 - 2275cm-1
is associated with NCO stretching. Presence
of NCO stretching band and all the above-mentioned bands
indicates formation of isocyanate terminated polyurethane
prepolymer.
0 500 1000 1500 2000 2500 3000 3500 4000
0
20
40
60
80
PPG1000
PPG400
Wavenumber (cm
-1
)
0
20
40
60
80
0
20
40
60
80 PPG2000
Transmittance(%)
0
20
40
60
PPG2000:400
PPG1000:400
PPG2700
0
20
40
60
80
0
20
40
60
80
Fig-1: IR spectra of the prepolymers synthesized using
different molecular weight of polyol
3.2 Influence of Soft Segment Length on the Physico-
Chemical Properties
The influence of different soft segment length on the physico-
chemical properties of isocyanate terminated polyurethane
prepolymer was shown from Fig 2 to 6. It was observed that as
the molecular weight of the polyol increases, the isocyanate
content of the prepolymer decreases. Mixing the polyol in 50 /
50 ratios gives isocyanate content in between their respective
counterparts.
The viscosity of the prepolymer decreases with increasing the
molecular weight of the polyol This is because of the fact that
viscosity of polyurethane prepolymer depends on the urethane
group content of the prepolymer. As the number of urethane
groups increases, the NH group and carbonyl group of
urethane linkage form strong physical crosslinking, thereby
increasing the stiffness of the network causing increase in
viscosity. The higher molecular weight polyol generates less
urethane groups thus having less viscosity in comparison to
lower molecular weight polyol which produces more urethane
groups [6].
The molecular weight of the prepolymer was found to be
higher in case of high molecular weight polyol due to its
longer chain length.
On observing the storage stability of the prepolymer, it was
found that the storage stability of the prepolymer was less in
case of prepolymer synthesized by using lower molecular
weight polyol. This is due to the generation of more urethane
groups in case of lower molecular weight polyol which
increases the physical crosslinking thereby decreasing the
flowability of the prepolymer and ultimately the storage time.
By mixing two polyols having different molecular weight in
50 / 50 ratio, the storage time was observed to be in between
their respective counterparts.
The set to touch time and tack free time of the prepolymer was
found to increase with increasing molecular weight of the
polyol. This is due to the fact that lower molecular weight
polyol generates more NCO terminated short chain segments,
thus creating more reactive sites for reaction with water which
in turn cause a decrease in set to touch time and tack free time
of the prepolymer. In case of higher molecular weight polyol,
less isocyanates end groups are produced for reaction with
water, thus having longer curing time.
Fig-2: Effect of polyol molecular weight on isocyanate
content of the prepolymer

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Fig-3: Effect of polyol molecular weight on viscosity of the
prepolymer
Fig-4: Effect of polyol molecular weight on weight average
molecular weight of the prepolymer
Fig-5: Effect of polyol molecular weight on storage time of
the prepolymer
Fig-6: Effect of polyol molecular weight on curing time of the
prepolymer
3.3 Influence of Soft Segment Length on the
Mechanical Properties
Results in Fig- 7, indicates that as the molecular weight of the
polyol increases, linear decrease in tensile strength and
increase in percent elongation was observed as the polymer
becomes increasingly soft with increase in chain length of the
soft segment. But in case of PPG 400, both the tensile strength
and percent elongation was observed to be low due to the
brittle nature of the polymer [7]. In case of mixed polyol i.e.
PPG1000 and PPG 400 in 50 / 50 ratio, the tensile strength
was found to be highest among all the polyurethane films.
Fig-7: Effect of polyol molecular weight on tensile strength
and percent elongation of the polyurethane film
3.4 Influence of Soft Segment Length on the Thermal
Properties
The thermal properties of the synthesized prepolymer were
investigated by DSC technique. For all the prepolymers only
one Tg was observed in the range from -34.14o
C to -58.43o
C
and it was found to be decreasing with increasing molecular

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weight of the polyol (Fig- 8). This is because of the fact that as
the soft segment length increases at a fixed hard segment
length, there rise an increased tendency of the hard segment to
be isolated in the domain of soft segment matrix. This
phenomenon resulted in a higher degree of phase separation
between hard and soft blocks, which produced a lower Tg
values. In the literature, it was reported that the phase
separation was enhance by increasing soft segment length [6,
8 , 9].
Fig-8 : DSC thermograms of the synthesized prepolymer
CONCLUSIONS
The isocyanate terminated polyurethane prepolymer was
synthesized by thermal polymerization technique using MDI
and PPG. Their formation was confirmed by FTIR which
shows characteristics absorption bands of polyurethane. The
Brookfield viscosity of the prepolymer decreases with increase
in chain length of the soft segment, whereas the molecular
weight and storage time was found to increases The curing
time of the prepolymer was found to increase with increasing
chain length of the soft segment i.e. with decrease in
isocyanate content. The results on mechanical property shows
that the tensile strength decreases with increasing molecular
weight of the soft segment whereas opposite trend was
observed in case of percent elongation of the polyurethane
film. PPG 400 was found to produce polyurethane films
having lower tensile strength and elongation due to its brittle
nature. Mixing of PPG 1000 with PPG 400 in 50 / 50 ratio
gives highest tensile strength among all the polyurethane
films. Lower Tg was observed in prepolymer having longer
soft segment due to its flexible nature.
ACKNOWLEDGEMENTS
The authors wish to thank and acknowledge Indian Council of
Medical Research, Govt of India for providing the financial
support for carrying out the study.
REFERENCES
[1] Sonal Desai, I.M Thakore, B.D Sarawade, Surekha
Devi, Effect of polyol and diisocyanates on thermo-
mechanical and morphological properties of
polyurethanes, European Polymer Journal 2000; 36,
711-725.
[2] Xia Dong Chen, Nan. Qiao Zhou and Hai Zhang,
Preparation and properties of cast polyurethane
elastomers with molecularly uniform hard segments
based on 2,4-toluene diisocyanate and 3,5 dimethyl
thiotoluenediame, J. Biomedical Science and
Engineering. , 2 , -253.
[3] Rajendran G.P, Mahadevan V, Srinivasan M,
Synthesis and properties of polyester based
polyurethane. Eur.Polym.J. 1982, 18: 953-956.
[4] J.H Saunders and K.C Frisch, Polyurethane: Chemistry
and Technology II, Technology, Interscience publisher,
US, 1964, pg. 8-12.
[5] J.H Saunders and K.C Frisch, Polyurethane: Chemistry
and Technology II, Technology, Interscience publisher,
US , 1964 pg. 480.
[6] D.K Chattopadhyay, K.V.S.N Raju, Structural
engineering of polyurethane coatings for high
performance applications, Prog. Polym. Sci. 2007, 32 :
352-418.
[7] Buckanin R.S, Catalyst for the curing of a water
curable isocyanate functional prepolymer. U.S. Pat
4,705,840, 1987.
[8] Sarawut Rimdusit, Tharathon Mongkhonsi, Pakawan
Kamonchaivanich, Kuljira Sujirote, Sunan
Thiptipakornl, Effect of polyol molecular weight on
the properties of benzoxazine urethane polymer alloys,
Polymer Engineering and Science, Nov 2008, 48(11) :
2238-2246.
[9] Sebastian Clau, Dirk J. Dijkstra, Joseph Gabriel, Oliver
Klausler, Mathias Malner, Walter Meckel, Peter Niemz,
Influence of chemical structure of PUR prepolymer on
thermal stability, International journal of adhesion and
adhesives, 2011, 31 : 513-523.

Effect of soft segment chain length on tailoring the properties of isocyanate terminated polyurethane prepolymer, a base material for polyurethane bandage

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Effect of soft segment chain length on tailoring the properties of isocyanate terminated polyurethane prepolymer, a base material for polyurethane bandage