This paper investigates the influence of the particle size of the red phosphor Ba[Mg2Al2N4]Eu2+ on the optical properties of 6000K conformal packaging white LEDs (CPW-LEDs). The study finds that increasing the particle size from 1 μm to 10 μm enhances the color rendering index (CRI) and color quality scale (CQS), with CRI increasing from 65 to 67 and CQS from 64 to 68. The findings suggest that the particle size significantly affects the optical performance of CPW-LEDs, providing recommendations for the LED industry.