3. 3
Thermoelectric Effect
• There is a relationship between the temperature of a conductor
and the kinetic energy of the free electrons.
• Thus, when a metal is subjected to a temperature gradient, the
free electrons will diffuse from the high temperature region to
the low temperature region where they have a lower kinetic
energy.
• The electron concentration gradient creates a voltage gradient
since the lattice atoms that constitute the positive charges are
not free to move.
• This voltage gradient will oppose the further diffusion of
electrons in the wire and a stable equilibrium will be established
with no current flow.
𝐾 . 𝐸=
3
2
𝑘𝐵 𝑇
4. 4
Thermoelectric Effect
• The “thermal power” of a material relates the balance of
thermal diffusion of the electrons to the electrical conductivity
of the metal and is unique for every conductor and usually
varies with temperature.
• Thus, a SINGLE conductor with its ends at differing temperatures
will have a voltage difference between the ends.
5. 5
Thermoelectric Effect
• The trick is to be able to measure the voltage at both ends of
the conductor and thus determine the temperature difference
between those ends.
• If we use the same type of wire to measure the voltage across
the original wire, the second wire will develop exactly the same
voltage difference when its ends are exposed to the same
temperatures as the original wire.
• Therefore, this effect cannot be measured with a pair of similar
wires.
• But because the voltage gradient is a function of the thermal
power, which is different for each type of metal, a second
conductor of a different type of wire can be used to measure the
original voltage gradient.
6. 6
Seebeck Effect
• Whenever two metals are joined together and the junction is at a
different temperature than the free ends of the conductors, the
free ends will have a potential difference between them.
• This difference of potential is a function of the absolute
temperature at the junction and the temperature of the free ends.
• Where,
– is emf produced in volts
– junction temperatures in K
– thermal transport constants for two metals
𝜀=∫
𝑇1
𝑇2
(𝑄𝐴 −𝑄𝐵 )𝑑𝑇
7. 7
Seebeck Effect
• Above equation describes the Seebeck effect.
• In practice, it is found that two constants are nearly independent
of temperature and that an approximate linear relationship exists
as,
• Where,
– is constant in V/K
– junction temperatures in K
𝜀=∫
𝑇1
𝑇2
(𝑄𝐴 −𝑄𝐵 )𝑑𝑇
𝜀=𝛼(𝑇1 −𝑇 2)
8. 8
Example-1
• Find the Seebeck emf for a material with . If the junction
temperatures are and .
Solution:
𝜀=𝛼(𝑇1 −𝑇 2)
𝜀=50𝜇(100−20)
𝜀=40𝑚𝑉
9. 9
Peltier Effect
• A useful extension of same thermoelectric properties occurs when
the reverse of the Seebeck effect is considered.
• An external voltage is applied to the system to cause a current to
flow in the circuit.
• Because of the different electro-thermal transportation properties
of the metals, it is found that one of the junction will be heated and
other cooled.
10. 10
Thermocouple
• To use the Seebeck effect as the basis of temperature sensor,
we need to establish definite relationship between the
measured emf of the thermocouple and the unknown
temperature.
• We see first that one temperature must already be known
because the Seebeck voltage is proportional to the difference
between junction temperatures.
• Further more every connection of different metals made in
thermocouple loop for measuring devices (e.g. extension
leads) will contribute and emf.
𝜀=𝛼(𝑇1 −𝑇2)
11. 11
Thermocouple
• To provide an output that is definite with respect to the
temperature to be measured an arrangement such as shown
below is used.
• This shows that the measurement junction is exposed to
environment whose temperature is to be measured.
• This junction is formed of Metal A and B.
12. 12
Thermocouple
• To use the thermocouple to measure the temperature
reference junction should be kept at constant temperature.
• In most industrial environments this would be difficult to
achieve if the measurement junction and reference junction
were close.
• Therefore the reference junction is moved to a remote
location by use of extension wires as shown below.